Certificate of Analysis
HEMP QUALITY ASSURANCE TEST

Sample Name:

GREEN GRUFF Organic Tinctures For Dogs (600 mg of CBD) Peanut Butter

Infused, Hemp

Date Issued:

03/02/2025

Serving Size:

1 milliliter

Total THC 23.760 mg/unit
Total CBD 568.770 mg/unit
Sum Cannabinoids 627.540 mg/unit
Total Cannabinoids 625.380 mg/unit

Sample Information

Sample Details

Sample ID:250224M037

Batch Number:GODRI4

Cultivator / Manufacturer

Show Details

Distributor / Tested For

Show Details

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Cannabinoid Analysis - Summary

Total THC: 23.760 mg/unit

Total CBD: 568.770 mg/unit

Sum of Cannabinoids: 627.540 mg/unit

Total Cannabinoids: 625.380 mg/unit

Density:0.9201 g/mL

Total THC/CBD is calculated using the following formulas to take into account the loss of a carboxyl group during the decarboxylation step:
Total THC = Δ9-THC + (THCa (0.877))
Total CBD = CBD + (CBDa (0.877))

Sum of Cannabinoids = Δ9-THC + THCa + CBD + CBDa + CBG + CBGa + THCV + THCVa + CBC + CBCa + CBDV + CBDVa + Δ8-THC + CBL + CBN + exo-THC + Δ8-THCV + Δ8-iso-THC + 9S-HHC + 9R-HHC + Δ10-THC + Δ9-THC Acetate

Total Cannabinoids = (Δ9-THC+0.877*THCa) + (CBD+0.877*CBDa) + (CBG+0.877*CBGa) + (THCV+0.877*THCVa) + (CBC+0.877*CBCa) + (CBDV+0.877*CBDVa) + Δ8-THC + CBL + CBN + exo-THC + Δ8-THCV + Δ8-iso-THC + 9S-HHC + 9R-HHC + Δ10-THC + Δ9-THC Acetate

Sum of Cannabinoids: The concentration of each individual cannabinoid added together as they are, without accounting for decarboxylation. This measurement is of particular importance for certain cannabis products that are not intended to be heated prior to application or consumption.

Total Cannabinoids: The concentration of each acidic cannabinoid, multiplied by 0.877 to account for the loss of molecular mass that happens as it is converted to a neutral cannabinoid when heated. Then this calculated concentration is added to the concentrations of the corresponding neutral cannabinoid already present. This corrected data is of particular importance to both producers and consumers of products intended to be heated prior to application or consumption.

Safety Analysis - Summary

Pesticides: Detected

Mycotoxins: ND

Residual Solvents: ND

Heavy Metals: ND

Microbiology (PCR): ND

Microbiology (Plating): ND

Foreign Material: Pass

Additives: Detected

View Complete Test Results:

Tested by high-performance liquid chromatography with diode-array detection (HPLC-DAD).

Method: QSP 1157 - Analysis of Cannabinoids by HPLC-DAD or QSP 34181 - Semisynthetic Cannabinoids Analysis by HPLC

Summary

Total THC: 23.760 mg/unit

9-THC+0.877*THCa)

Total CBD: 568.770 mg/unit

(CBD+0.877*CBDa)

Total Cannabinoids: 625.380 mg/unit

Total CBG: 5.670 mg/unit

Total CBG (CBG+0.877*CBGa)

Total THCV: ND

Total THCV (THCV+0.877*THCVa)

Total CBC: 20.010 mg/unit

Total CBC (CBC+0.877*CBCa)

Total CBDV: 4.080 mg/unit

Total CBDV (CBDV+0.877*CBDVa)

Learn more

The cannabis plant contains dozens of active compounds called cannabinoids. These compounds are the primary contributors to the psychoactive effects of cannabis.

Cannabinoid testing determines the potency of a sample to aid in dosage considerations.

Cannabinoid Test Results

03/02/2025

Result Views

Swipe left on table to see additional columns

Compound LOD/LOQ
(mg/mL)
Measurement
Uncertainty
(mg/mL)
Result
(mg/mL)
Result
(%)
Cannabidiol (CBD) 0.004 / 0.011 ±0.6887 18.463 2.0066
Δ9 Tetrahydrocannabinol (Δ9THC) 0.002 / 0.014 ±0.0435 0.792 0.0861
Cannabichromene (CBC) 0.003 / 0.010 ±0.0210 0.653 0.0710
Cannabidiolic Acid (CBDa) 0.001 / 0.026 ±0.0161 0.566 0.0615
Cannabigerol (CBG) 0.002 / 0.006 ±0.0092 0.189 0.0205
Cannabidivarin (CBDV) 0.002 / 0.012 ±0.0055 0.136 0.0148
Cannabinol (CBN) 0.001 / 0.007 ±0.0023 0.080 0.0087
Cannabicyclol (CBL) 0.003 / 0.010 ±0.0008 0.023 0.0025
Cannabichromenic Acid (CBCa) 0.001 / 0.015 ±0.0006 0.016 0.0017
Cannabigerolic Acid (CBGa) 0.002 / 0.007 N/A ND ND
Tetrahydrocannabivarin (THCV) 0.002 / 0.012 N/A ND ND
Tetrahydrocannabinolic Acid (THCa) 0.001 / 0.005 N/A ND ND
Cannabidivarinic Acid (CBDVa) 0.001 / 0.018 N/A ND ND
Tetrahydrocannabivarinic Acid (THCVa) 0.002 / 0.019 N/A ND ND
9R-Hexahydrocannabinol (9R-HHC) 0.027 / 0.089 N/A ND ND
9S-Hexahydrocannabinol (9S-HHC) 0.027 / 0.090 N/A ND ND
Exo-Tetrahydrocannabinol (Exo-THC) 0.028 / 0.093 N/A ND ND
∆8 Tetrahydrocannabinol (Δ8THC) 0.01 / 0.02 N/A ND ND
Δ10 Tetrahydrocannabinol (Δ10THC) 0.024 / 0.078 N/A ND ND
∆8 Tetrahydrocannabivarin (Δ8THCV) 0.012 / 0.039 N/A ND ND
∆8 Isotetrahydrocannabinol (Δ8-iso-THC) 0.025 / 0.084 N/A ND ND
Δ9 Tetrahydrocannabinol Acetate (Δ9THC Acetate) 0.023 / 0.077 N/A ND ND
SUM OF CANNABINOIDS 20.918 mg/mL 2.2734%
Unit Mass:

30 milliliters

/

Serving Size:

1 milliliter

Swipe left on table to see additional columns

Δ9-THC per Unit 23.760 mg/unit
Δ9-THC per Serving 0.792 mg/serving
Total THC per Unit 23.760 mg/unit
Total THC Per Serving 0.792 mg/serving
CBD per Unit 553.890 mg/unit
CBD per Serving 18.463 mg/serving
Total CBD per Unit 568.770 mg/unit
Total CBD per Serving 18.959 mg/serving
Sum of Cannabinoids per Unit 627.540 mg/unit
Sum of Cannabinoids per Serving 20.918 mg/serving
Total Cannabinoids per Unit 625.380 mg/unit
Total Cannabinoids per Serving 20.846 mg/serving
Density Test Result

0.9201 g/mL Tested 03/02/2025 Method: QSP 7870 - Sample Preparation

Learn more

The cannabis plant contains dozens of active compounds called cannabinoids. These compounds are the primary contributors to the psychoactive effects of cannabis.

Cannabinoid testing determines the potency of a sample to aid in dosage considerations.

Pesticide and plant growth regulator analysis utilizing high-performance liquid chromatography-mass spectrometry (HPLC-MS) or gas chromatography-mass spectrometry (GC-MS).

*GC-MS utilized where indicated.

Method: QSP 1212 - Analysis of Pesticides and Mycotoxins by LC-MS or QSP 1213 - Analysis of Pesticides by GC-MS

Pesticide Test Results

03/01/2025

DETECTED

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Compound LOD/LOQ
(μg/g)
Measurement
Uncertainty
(μg/g)
Result
(μg/g)
Abamectin 0.032 / 0.097 N/A ND
Acephate 0.006 / 0.018 N/A ND
Acequinocyl 0.009 / 0.027 N/A ND
Acetamiprid 0.016 / 0.049 N/A ND
Aldicarb 0.030 / 0.090 N/A ND
Allethrin 0.030 / 0.092 N/A ND
Atrazine 0.006 / 0.019 N/A ND
Azadirachtin 0.082 / 0.248 N/A ND
Azoxystrobin 0.003 / 0.009 N/A ND
Benzovindiflupyr 0.003 / 0.009 N/A ND
Bifenazate 0.003 / 0.009 N/A ND
Bifenthrin 0.021 / 0.064 N/A ND
Boscalid 0.003 / 0.009 N/A ND
Buprofezin 0.006 / 0.019 N/A ND
Captan 0.045 / 0.135 N/A ND
Carbaryl 0.007 / 0.020 N/A ND
Carbofuran 0.003 / 0.008 N/A ND
Chlorantraniliprole 0.006 / 0.018 N/A ND
Chlordane* 0.010 / 0.032 N/A ND
Chlorfenapyr* 0.005 / 0.015 N/A ND
Chlormequat chloride 0.022 / 0.066 N/A ND
Chlorpyrifos 0.013 / 0.039 N/A ND
Clofentezine 0.003 / 0.009 N/A ND
Clothianidin 0.008 / 0.025 N/A ND
Coumaphos 0.003 / 0.010 N/A ND
Cyantraniliprole 0.003 / 0.010 N/A ND
Cyfluthrin 0.052 / 0.159 N/A ND
Cypermethrin 0.051 / 0.153 N/A ND
Cyprodinil 0.003 / 0.008 N/A ND
Daminozide 0.026 / 0.077 N/A ND
Deltamethrin 0.059 / 0.180 N/A ND
Diazinon 0.006 / 0.017 N/A ND
Dichlorvos (DDVP) 0.012 / 0.038 N/A ND
Dimethoate 0.003 / 0.009 N/A ND
Dimethomorph 0.016 / 0.050 N/A ND
Dinotefuran 0.010 / 0.030 N/A ND
Diuron 0.013 / 0.040 N/A ND
Dodemorph 0.012 / 0.035 N/A ND
Endosulfan sulfate 0.016 / 0.048 N/A ND
Endosulfan-α* 0.004 / 0.014 N/A ND
Endosulfan-β* 0.006 / 0.019 N/A ND
Ethoprophos 0.003 / 0.009 N/A ND
Etofenprox 0.014 / 0.042 N/A ND
Etoxazole 0.007 / 0.020 N/A ND
Etridiazole* 0.002 / 0.005 N/A ND
Fenhexamid 0.003 / 0.008 N/A ND
Fenoxycarb 0.003 / 0.010 N/A ND
Fenpyroximate 0.007 / 0.020 N/A ND
Fensulfothion 0.003 / 0.010 N/A ND
Fenthion 0.003 / 0.010 N/A ND
Fenvalerate 0.033 / 0.099 N/A ND
Fipronil 0.003 / 0.010 N/A ND
Flonicamid 0.007 / 0.022 N/A ND
Fludioxonil 0.003 / 0.010 N/A ND
Fluopyram 0.003 / 0.009 N/A ND
Hexythiazox 0.003 / 0.010 N/A ND
Imazalil 0.003 / 0.009 N/A ND
Imidacloprid 0.003 / 0.010 N/A ND
Iprodione 0.077 / 0.233 N/A ND
Kinoprene 0.077 / 0.233 N/A ND
Kresoxim-methyl 0.006 / 0.019 N/A ND
λ-Cyhalothrin 0.068 / 0.206 N/A ND
Malathion 0.003 / 0.009 N/A ND
Metalaxyl 0.003 / 0.010 N/A <LOQ
Methiocarb 0.003 / 0.008 N/A ND
Methomyl 0.008 / 0.025 N/A ND
Methoprene 0.172 / 0.521 N/A ND
Mevinphos 0.008 / 0.024 N/A ND
MGK-264 0.015 / 0.047 N/A ND
Myclobutanil 0.003 / 0.009 N/A ND
Naled 0.021 / 0.064 N/A ND
Novaluron 0.002 / 0.005 N/A ND
Oxamyl 0.017 / 0.051 N/A ND
Paclobutrazol 0.003 / 0.010 N/A ND
Parathion-methyl 0.016 / 0.050 N/A ND
Pentachloronitrobenzene (Quintozene)* 0.004 / 0.012 N/A ND
Permethrin 0.056 / 0.168 N/A ND
Phenothrin 0.016 / 0.047 N/A ND
Phosmet 0.007 / 0.020 N/A ND
Piperonyl Butoxide 0.010 / 0.029 N/A ND
Pirimicarb 0.003 / 0.009 N/A ND
Prallethrin 0.015 / 0.046 N/A ND
Propiconazole 0.027 / 0.080 N/A ND
Propoxur 0.003 / 0.008 N/A ND
Pyraclostrobin 0.003 / 0.010 N/A ND
Pyrethrins 0.016 / 0.049 N/A ND
Pyridaben 0.005 / 0.017 N/A ND
Pyriproxyfen 0.003 / 0.009 N/A ND
Resmethrin 0.013 / 0.039 N/A ND
Spinetoram 0.003 / 0.010 N/A ND
Spinosad 0.003 / 0.010 N/A ND
Spirodiclofen 0.031 / 0.093 N/A ND
Spiromesifen 0.016 / 0.050 N/A ND
Spirotetramat 0.003 / 0.010 N/A ND
Spiroxamine 0.020 / 0.062 N/A ND
Tebuconazole 0.003 / 0.010 N/A ND
Tebufenozide 0.003 / 0.008 N/A ND
Teflubenzuron 0.007 / 0.022 N/A ND
Tetrachlorvinphos 0.003 / 0.008 N/A ND
Tetramethrin 0.021 / 0.063 N/A ND
Thiabendazole 0.006 / 0.020 N/A ND
Thiacloprid 0.003 / 0.009 N/A ND
Thiamethoxam 0.003 / 0.010 N/A ND
Thiophanate-methyl 0.013 / 0.040 N/A ND
Trifloxystrobin 0.003 / 0.009 N/A ND

Mycotoxin analysis utilizing high-performance liquid chromatography-mass spectrometry (HPLC-MS).

Method: QSP 1212 - Analysis of Pesticides and Mycotoxins by LC-MS

Mycotoxin Test Results

03/01/2025

ND

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Compound LOD/LOQ
(μg/kg)
Measurement
Uncertainty
(μg/kg)
Result
(μg/kg)
Aflatoxin B1 1.6 / 5.0 N/A ND
Aflatoxin B2 1.4 / 4.1 N/A ND
Aflatoxin G1 1.6 / 4.9 N/A ND
Aflatoxin G2 1.6 / 5.0 N/A ND
Ochratoxin A 1.6 / 5.0 N/A ND
Total Aflatoxin ± ND

Residual Solvent analysis utilizing gas chromatography-mass spectrometry (GC-MS).

Method: QSP 1204 - Analysis of Residual Solvents by GC-MS

Residual Solvents Test Results

02/28/2025

ND

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Compound LOD/LOQ
(μg/g)
Measurement
Uncertainty
(μg/g)
Result
(μg/g)
Propane 0.234 / 0.781 N/A ND
2-Methylpropane (Isobutane) 0.052 / 0.173 N/A ND
n-Butane 0.019 / 0.063 N/A ND
Total Butanes ± ND
2-Methylbutane (Isopentane) 0.310 / 1.035 N/A ND
2,2-Dimethylpropane (Neopentane) 0.035 / 0.117 N/A ND
n-Pentane 0.310 / 1.033 N/A ND
Total Pentanes ± ND
2,2-Dimethylbutane (Neohexane) 9.831 / 32.77 N/A ND
2,3-Dimethylbutane / 2-Methylpentane (Isohexane) 0.381 / 1.271 N/A ND
3-Methylpentane 0.109 / 0.365 N/A ND
n-Hexane 0.110 / 0.366 N/A ND
Total Hexanes ± ND
Cyclohexane 0.357 / 1.190 N/A ND
2,2-Dimethylpentane (Neoheptane) 0.493 / 1.642 N/A ND
2,3-Dimethylpentane 1.009 / 3.365 N/A ND
2,4-Dimethylpentane 0.737 / 2.458 N/A ND
3,3-Dimethylpentane 0.198 / 0.660 N/A ND
2,2,3-Trimethylbutane (Triptane) 0.521 / 1.738 N/A ND
2-Methylhexane (Isoheptane) 0.610 / 2.034 N/A ND
3-Methylhexane 0.235 / 0.785 N/A ND
3-Ethylpentane 0.304 / 1.012 N/A ND
n-Heptane 13.12 / 43.72 N/A ND
Total Heptanes ± ND
Cycloheptane 0.597 / 1.989 N/A ND
Benzene 0.089 / 0.295 N/A ND
Toluene 0.115 / 0.382 N/A ND
Cumene 0.180 / 0.600 N/A ND
1,3-Dimethylbenzene (m-Xylene) / 1,4-Dimethylbenzene (p-Xylene) 0.451 / 1.502 N/A ND
1,2-Dimethylbenzene (o-Xylene) 0.387 / 1.289 N/A ND
Ethylbenzene 0.370 / 1.233 N/A ND
Total Xylenes ± ND
Methanol 53.92 / 163.4 N/A ND
Ethanol 8.984 / 27.23 N/A ND
1-Propanol 1.540 / 5.133 N/A ND
2-Propanol (Isopropyl Alcohol) 8.421 / 25.52 N/A ND
1-Butanol 0.475 / 1.582 N/A ND
2-Butanol 7.248 / 24.16 N/A ND
1-Pentanol 1.461 / 4.869 N/A ND
Acetone 10.59 / 32.08 N/A ND
2-Butanone 0.169 / 0.564 N/A ND
Tetrahydrofuran 0.622 / 2.075 N/A ND
Ethyl Ether 0.197 / 0.658 N/A ND
Ethylene Glycol 3.803 / 12.68 N/A ND
2-Ethoxyethanol 1.235 / 4.118 N/A ND
1,2-Dimethoxyethane 2.116 / 7.052 N/A ND
1,4-Dioxane 0.468 / 1.558 N/A ND
Ethylene Oxide 0.253 / 0.844 N/A ND
Ethyl Acetate 1.123 / 3.745 N/A ND
Isopropyl Acetate 0.347 / 1.158 N/A ND
Chloroform 0.251 / 0.838 N/A ND
Dichloromethane (Methylene Chloride) 2.651 / 8.838 N/A ND
Trichloroethylene 0.299 / 0.996 N/A ND
1,2-Dichloroethane 0.162 / 0.541 N/A ND
1,1-Dichloroethene 0.185 / 0.616 N/A ND
1,2-Dichloroethene 0.428 / 1.427 N/A ND
Sulfolane 47.66 / 158.9 N/A ND
Dimethyl Sulfoxide 6.168 / 20.56 N/A ND
Acetonitrile 1.595 / 4.833 N/A ND
Pyridine 0.407 / 1.355 N/A ND
N,N-Dimethylacetamide 0.127 / 0.422 N/A ND
N,N-Dimethylformamide 0.946 / 3.153 N/A ND

Total Butanes = n-Butane + 2-Methylpropane (Isobutane)

Total Pentanes = n-Pentane + 2-Methylbutane (Isopentane) + 2,2-Dimethylpropane (Neopentane)

Total Hexanes = n-Hexane + 2,2-Dimethylbutane (Neohexane) + 2,3-Dimethylbutane / 2-Methylpentane (Isohexane) + 3-Methylpentane

Total Heptanes = 2,2-Dimethylpentane (Neoheptane) + 2,3-Dimethylpentane + 2,4-Dimethylpentane + 3,3-Dimethylpentane + 2,2,3-Trimethylbutane (Triptane) + 2-Methylhexane (Isoheptane) + 3-Methylhexane + 3-Ethylpentane + n-Heptane

Total Xylenes = 1,2-Dimethylbenzene (o-Xylene) + 1,3-Dimethylbenzene (m-Xylene) / 1,4-Dimethylbenzene (p-Xylene) + Ethylbenzene

Heavy metal analysis utilizing inductively coupled plasma-mass spectrometry (ICP-MS).

Method: QSP 1160 - Analysis of Heavy Metals by ICP-MS

Heavy Metals Test Results

02/28/2025

ND

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Compound LOD/LOQ
(μg/g)
Measurement
Uncertainty
(μg/g)
Result
(μg/g)
Arsenic 0.02 / 0.1 N/A ND
Boron 0.21 / 0.64 N/A ND
Cadmium 0.02 / 0.05 N/A ND
Chromium 0.12 / 0.35 N/A ND
Cobalt 0.10 / 0.30 N/A ND
Copper 0.14 / 0.44 N/A ND
Lead 0.04 / 0.1 N/A ND
Lithium 0.10 / 0.31 N/A ND
Manganese 0.13 / 0.40 N/A ND
Mercury 0.002 / 0.01 N/A ND
Molybdenum 0.15 / 0.44 N/A ND
Nickel 0.13 / 0.39 N/A ND
Selenium 0.5 / 1.5 N/A ND
Silver 0.15 / 0.47 N/A ND
Sulfur 78 / 235 N/A ND
Titanium 0.12 / 0.38 N/A ND
Tungsten 0.10 / 0.32 N/A ND
Zinc 0.8 / 2.5 N/A ND

Analysis conducted by polymerase chain reaction (PCR) and fluorescence detection of microbiological contaminants. And Analysis conducted by 3MTM PetrifilmTM and plate counts of microbiological contaminants.

Method: QSP 1221 - Analysis of Microbiological Contaminants

Microbiology Test Results (PCR)

03/01/2025

ND

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Compound Result
(cfu/g)
Yersinia spp. ND
Salmonella spp. ND
Candida albicans ND
Aspergillus niger ND
Aspergillus flavus ND
Campylobacter spp. ND
Aspergillus terreus ND
Aspergillus fumigatus ND
Staphylococcus aureus ND
Listeria monocytogenes ND
Pseudomonas aeruginosa ND
Bile-Tolerant Gram-Negative Bacteria ND
Shiga toxin-producing Escherichia coli ND
Microbiology Test Results (PLATING)

03/01/2025

ND

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Compound Result
(cfu/g)
Coliforms ND
Escherichia coli ND
Staphylococcus spp. ND
Total Yeast and Mold ND
Total Aerobic Bacteria ND
Total Enterobacteriaceae ND

Visual analysis includes, but is not limited to, sand, soil, cinders, dirt, mold, hair, insect fragments, and mammalian excreta.

Method: QSP 1226 - Analysis of Foreign Material in Cannabis and Cannabis Products

Foreign Material Test Results

02/25/2025

PASS

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Compound Action Limit Result Result
Hair Count > 1 per 3 grams 0.0 Pass
Insect Fragment Count > 1 per 3 grams 0.0 Pass
Mammalian Excreta Count > 1 per 3 grams 0.0 Pass
Total Sample Area Covered by Mold >25% None Pass
Total Sample Area Covered by Sand, Soil, Cinders, or Dirt >25% None Pass
Total Sample Area Covered by an Imbedded Foreign Material >25% None Pass

Tested by high-performance liquid chromatography with diode-array detection (HPLC-DAD).

Method: QSP 6793 - Analysis of Vitamin E by HPLC-DAD

Additives Test Results

03/01/2025

DETECTED

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Compound LOD/LOQ
(mg/g)
Measurement
Uncertainty
(mg/g)
Result
(mg/g)
Result
(%)
α-Tocopherol 0.069 / 0.209 N/A <LOQ <LOQ
δ-Tocopherol 0.061 / 0.183 N/A ND ND
Tocopheryl Acetate 0.047 / 0.143 N/A ND ND
ß-Tocopherol / γ-Tocopherol 0.093 / 0.281 ±0.0081 0.353 0.0353

* ß-Tocopherol / γ-Tocopherol reported as a sum

Notes

COA Notes:

Sample unit mass provided by client.

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